基于MOF (Cu)@biochar气凝胶的制备及其在缓释氮肥上的应用

以羧甲基纤维素(CMC)、明胶和MOF(Cu)@biochar为原料,采用简单有效的冷冻干燥方法制备了(CMC/Gelatin/MOF(Cu)@biochar)杂化气凝胶,并用傅里叶变换红外光谱(FT-IR)、热重分析(TG)、X射线粉末衍射(XRD)、扫描电镜(SEM)和X射线光电子能谱(XPS)技术对其进行了表征;研究了MOF(Cu)@biochar含量、pH和不同的盐水溶液对杂化气凝胶溶胀行为的影响;以该气凝胶负载氯化铵,制备了一种新型缓释肥料(SRF),并研究了含2%(wt)SRF的沙性土壤的保水能力;SRF在土壤中第30天的累积释放率为79.4%;肥料在土壤中释放符合非Fickian扩散和阳离子交换的协同作用机理。     

On the inflation and deflation dynamics of liquid-filled,hyperelastic balloons

We derive a reduced-order model describing the inflation and deflation dynamics of a liquid-filled hyperelastic balloon, focusing on inviscid laminar flow and the extensional motion of the balloon. We initially study the flow and pressure fields for dictated motion of the solid, which throughout deflation are obtained by solving the potential problem. However, during inflation, flow separation creates a jet within the balloon, requiring a different approach. The analyses of both flow regimes lead to a simple piecewise model, describing the fluidic pressure during inflation and deflation, which is verified by finite element computations. We then use a variational approach to derive the equation describing the interaction between the extensional mode of the balloon and the entrapped fluid, yielding a nonlinear hybrid oscillator equation. Analytical and graphical investigations of the suggested model are presented, shedding light on its static and dynamic behaviour under different operating conditions. Our simplified model and its underlying assumptions are verified utilizing a fully coupled finite element scheme, showing excellent agreement.     

曲面相机阵列多分辨成像方法

针对现有成像系统因数据冗余而无法兼顾大视场、高分辨、高效性的问题,结合人眼视网膜变分辨成像和并列式复眼成像原理,设计一种多分辨率成像的复合仿生成像系统.该成像系统按照球面和平面兼顾的曲面布局方式,利用11个相机镜头构建相机阵列,组成了四个等级分辨率的子眼拍摄模块.通过物距100 m的远景实验和物距10 m的近景实验发现,该系统在实现高分辨成像的同时,获得总视场达150.8°×37.8°.多分辨率成像实验结果表明,该系统获取的图像的分辨率从中心视场到边缘视场逐渐降低,并且相较于中心清晰全视场成像,四级分辨率成像的拼接图像数据量减少了17.2倍的数据冗余.     

Sonochemical approach for synthesis of zinc oxide-poly methyl methacrylate hybrid nanoparticles and its application in corrosion inhibition

Hybrid nanoparticles (HNPs) with zinc oxide and polymethyl metha acrylate (inorganic/ polymer) were synthesized through the exploitation of ultrasound approach. The synthesized HNPs were further characterized employing transmission electron microscopy and x-ray diffraction. ZnO-PMMA based HNPs exhibit excellent protection properties to mild steel from corrosion when gets exposed to acidic condition. Electrochemical impendence spectroscopy (EIS) analysis was accomplished to evaluate the corrosion inhibition performance of MS panel coated with 2 wt% or 4 wt% of HNPs and its comparison with bare panel and that of loaded with only standard epoxy coating., Tafel plot and Nyquist plot analysis depicted that the corrosion current density (I_corr) decreases from 16.7 A/m² for bare material to 0.103 A/m² for 4% coating of HNPs. Applied potential (E_corr) values shifted from negative to positive side. These results were further supported by qualitative analysis. The images taken over a period of time indicated the increase in lifetime of MS panel from 2 to 3 days for bare panel to 10 days for HNPs coated panel, showing that ZnO-PMMA HNPs have potential application in metal protection from corrosion by forming a passive layer.     

Mechanical characterization of a new Kevlar/Flax/epoxy hybrid composite in a sandwich structure

Natural fibers are inexpensive, biodegradable, and have similar specific properties to some synthetic fibers. Hardly any previous investigations exist of a composite made of multiple layers of pure Kevlar fiber fabric and pure Flax fiber fabric in a “sandwich structure”, but it only measured impact properties. The composite was made of 12 Flax/epoxy layers at the core in 3 possible configurations (i.e. [0]_12F, [0/90]_6F, or [±45]_6F) that were sandwiched by 2 Kevlar/epoxy layers (i.e. plain weave) on each side. This study showed maximum change in the mechanical properties with respect to Flax/Epoxy for tension (+137.85% in E_T, and +171.22% in σ_UT), compression (+171.22% in E_c, and −10.6% in σ_UC), 3-point bending (−11.54% in E_B, and +2.19 in σ_UB), torsion (−5.31% in G, and 395.82% in τ), and water absorption (60.04%). This novel hybrid composite may be useful for research and industry applications.     

Bi/Bi_2O_3 nanoparticles supported on N-doped reduced graphene oxide for highly efficient CO_2 electroreduction to formate

Electrocatalytic CO_2 reduction(CO_2 ER) into formate is a desirable route to achieve efficient transformation of CO_2 to value-added chemicals,however,it still suffers from limited catalytic activity and poor selectivity.Herein,we develop a hybrid electrocatalyst composed of bismuth and bismuth oxide nanoparticles(NPs) supported on nitrogen-doped reduced graphene oxide(Bi/Bi_2 O_3/NrGO) nanosheets prepared by a combined hydrothermal with calcination treatment.Thanks to the combination of undercoordinated sites and strong synergistic effect between Bi and Bi_2 O_3,Bi/Bi_2 O_3/NrGO-700 hybrid displays a promoted CO2 ER catalytic performance and selectivity for formate production,as featured by a small onset potential of-0.5 V,a high current density of-18 mA/cm~2,the maximum Faradaic efficiency of85% at-0.9 V,and a low Tafel slope of 166 mV/dec.Experimental results reveal that the higher CO_2 ER performance of Bi/Bi_2 O_3/NrGO-700 than that of Bi NPs supported on NrGO(Bi/NrGO) can be due to the partial reduction of Bi_2 O_3 NPs into Bi,which significantly increases undercoordinated active sites on Bi NPs surface,thus boosting its CO_2 ER performance.Furthermore,a two-electrode device with Ir/C anode and Bi/Bi_2 O_3/NrGO-700 cathode could be integrated with two alkaline batteries or a planar solar cell to achieve highly active water splitting and CO_2 ER.     

基于实际路网情境的配送车辆调度优化

在实际路网情境下结合车道数、车道宽度、路口信号灯设置等路网物理特性,构建了考虑综合交通阻抗的多车型车辆调度模型,提出了两阶段求解策略:第1阶段设计了改进A-star精确解算法用于计算客户时间距离矩阵;第2阶段针对实际路网的特征设计了混合模拟退火算法求解调度方案。以大连市某配送中心运营实例进行路网情境仿真试验,结果表明:改进A-star算法较改进Dijkstra算法具有更短的路径搜索时间;混合模拟退火算法求解结果较实际调度方案优化了13.1% 的综合成本;路网增流、区域拥堵和路段禁行三类路网情境均能对配送方案的车辆配置、路径选择、客户服务次序、作业时间和违约费用等5方面内容产生干扰,调度计划的制定需要详细考虑这些因素的变化。     

The anti-HIV potential of imidazole,oxazole and thiazole hybrids: A mini-review

Human immunodeficiency virus (HIV) especially HIV-1 infection and its progression to acquired immune deficiency syndrome (AIDS) remains a significant global health challenge. The advent of the highly active antiretroviral therapy (HAART) has greatly extended the life expectancy of patients living with HIV, but it has become evident that long-term HAART will not eliminate the HIV reservoir and cure the infection. Moreover, the drug resistance and undesirable side effects hamper efficacious therapy, creating an urgent need to develop novel, more effective and less toxic anti-HIV therapeutics. Imidazole, oxazole and thiazole with two heteroatoms at meta-position of five-membered rings are fascinating structures and constitute an important class of heterocycles in drug discovery. Their derivatives could exert the anti-HIV activity through diverse mechanisms and possess promising antiviral activity against both drug-sensitive and drug-resistant HIV strains. This review summarizes the research progress made regarding the anti-HIV potential of imidazole, oxazole and thiazole hybrids, and the structure–activity relationships (SARs) are also discussed to facilitate further rational design of more effective candidates, covering articles published from 2012 to 2022.